<10% of natural gas plants recover helium. All of them extract it. The remaining >90% vent it into the atmosphere. This is an engineering / money problem, not a physics problem.
It becomes a larger problem as the world moves away from fossil fuels like natural gas.
I'm not a chemist but are there really no alternatives? Running fusion plants to make helium seems very unlikely to become cost effective, but it would be quite the sci-fi future if we filled party balloons by bombarding hydrogen with free protons.
I guess there aren't any easy molecules to break apart to get helium either since its a noble gas. No hydrolyses type solutions because there aren't any molecules that incorporate helium. I guess radioactive decay, but even that is ultimately limited over long enough timescales.
The article itself spells out several alternatives to buying continuous amounts of Helium: high temperature semiconductors and zero boil-off systems that don't require a continual supply.
All these "we're going to run out" stories pretend that engineering cannot adapt to changing cost structures, which is just total nonsense.
Sure, there is nothing that can be directly substituted for how we use Helium today, but clearly we're using Helium inefficiently today and the answer is that once markets force us to change, we will find more efficient ways.
> It becomes a larger problem as the world moves away from fossil fuels like natural gas.
I actually remember a similar problem from some compound that was mainly formed as a byproduct of some old Canadian nuclear reactor design. As the tech gets phased out, the material is no longer available in significant quantities, with consequences for a projects that need it (like Iter).
Some things can be cheap if they are produced as a byproduct, but very expensive if they have to be obtained directly.
There are many cases in the news of accidents with sometimes a large number of party balloons filled with hydrogen or other flammable gases.
One of the larger episodes was in 2012 in Armenia, where thousands of balloons exploded during a meeting, injuring 154 people, of which 4 seriously (the video is of poor quality): https://www.youtube.com/watch?v=jWEm2sS7Dw8
a party balloon - say a cubic foot - is about 2g of hydrogen. Involves 16g of oxygen. So we're talking 18g of very fast burning, borderline detonating mass. Releases 240 KJ of energy.
To compare the hand grenade - 60g TNT https://en.wikipedia.org/wiki/F-1_grenade_(Russia) - releases the same 240 KJ of energy.
I had a science teacher that did this in class, then taped a match on the end of a yardstick and held it under the balloon. They made quite a bang. I wouldn't want to be right next to it when it went off.
While hydrogen-air mixes explode really readily (outstandingly wide flammability and pretty wide detonation range), and the energy released is considerable for the weight, the actual explosion does not produce a particularly high overpressure wave.
That's because the starting density of the hydrogen air mixes at near atmospheric pressure (such as in a balloon) is pretty low. Also, the balloon does not significantly contain the explosion, which reduces the danger a lot. I would not want to do it in a glass container.
My chemistry teacher told us how once when he ignited helium in a test tube, the tube broke and he ended up with pieces of glass embedded in his skin. The students had face masks and he was looking the other way "just in case" for this "safe" experiment but he could have easily been blinded.
Things can always go wrong. We probably shouldn't strive for 100% safety because they we'd spend our lives in a padded cell. But we also shouldn't assume things are safe because they're common or routine.
Along with the other commenter, I'll add that a classroom is usually a lot bigger than a home dining room or other domestic party locations. That size also helps things dissipate instead of reflect. Not sure by how much but I'm sure it does something.
We did this. One balloon with plain air. One with pure hydrogen. One with 50/50 hydrogen and air. The one with pure hydrogen popped closer in magnitude to the pure air than it was to the 50/50 mix.
ETA: I may be misremembering, the more I think about it, the more I recall that we did not use air, we did use pure oxygen. Not like it was hard to get (and we had lots more interesting stuff than that in the lab, this was the 80s...). But the outcome I do remember. The entire point of the experiment was to examine the difference between the individual pure elements and the mix. We expected the pure hydrogen to be far more interesting than it turned out.
Pure hydrogen in a balloon produces a low, loud, very satisfying bang. Completely different from a sound of an air balloon popping. Here is a video from a very good Royal Society of Chemistry demonstration series on various unusual combustion process:
Hydrogen mixed with air or with oxygen produces an ear piercing supersonic detonation, exceedingly loud and unpleasant. Not recommended for demonstrations.
As a kid I took a lot of classes at the Lawrence Hall of Science in Berkeley, which was paradise for fledgling nerds. On the last day they would have a little closing ceremony with some cute little science experiment. One of my favorites was "Going Out With A Bang".
The instructors would bring out a helium balloon and a candle on a meter stick. The balloon goes pop, huzzah.
Then the twist. "Hey, wanna do it again?" All the kids would be like "meh, I guess?" They would then bring out a balloon full of hydrogen (maybe some oxygen too?). It would look identical to the first one, floating there tethered to the lab bench.
When the candle hit the second one, it made a white flash and a really sharp BANG. It was an order of magnitude louder, and you could hear the transient bouncing off the walls and echoing in the halls. It made an impression.
As usual - 'there is scarcity of XYZ' -> price it accordingly, and markets will align quickly. Dont expecr private companies to have long term thinking, thats not how bonuses for those steering the wheel are set up.
I’m not really worried about any potential helium shortage. We are actually really good at extracting it, the problem is purely economics and as soon as prices get to the point where investment is warranted then there will continue to be adequate supplies. The main issue right now is the proper demand increase forecasts do not align with potential investments costs and helium extraction investment does just not make much economic sense given current forecast Helium costs.
Recently had to deal with radon in a basement, leading me to a fun side trek of learning about uranium decay (it has been a lot of years since chemistry classes).
When you hear about alpha decay of radioactive materials, that is the matter spitting off a highly ionized helium nucleus, freshly birthed into this world. That He nucleus rapidly steals electrons from matter, which is how it can be dangerous to human cells if ingested.
All of that helium underground is the result of alpha decay, and a single uranium-238 element will birth 8 helium atoms as it transitions through a series of metals and one gas (radon), then finally finding stability as Pb206. U235 will birth 7, becoming Pb207.
Anyways, found that fascinating. It's just happenstance that helium often gets blocked exiting the crust by the same sort of structures that block natural gas from escaping, and they are an odd-couple sharing little in common.
One other fun fact -- radon only has a half life of 3.8 days. Uranium becomes thorium becomes radium, then radon where it has an average 3.8 days to seep out of the Earth and into our basements, where it then becomes radioactive metals that attach to dust, get breathed in (or eaten) and present dangers. In the scale of things, crazy. Chemistry is fascinating.
It looks like that by simply reducing use in welding, lifting, and purging gas (all with clear alternatives) and maybe also 'leak detection' and 'other' (not expounded on in the article), they can fill in for the entire Qatari output, and that's without including extra production and recycling which is quiet possible.
For diving, there has been some experimental use of hydrogen as a partial replacement for helium in breathing gas mixtures. This obviously increases the risk of fires and the physiological effects aren't fully understood. But it might eventually be used in commercial, military, and exploration diving for those cases where we need to send humans really deep and using an atmospheric suit isn't an option. Regular sport divers will probably never breathe hydrogen.
I really enjoyed this oddlots podcast episode that covered similar points and had a lot of "wat" moments for me, including the US selling off its strategic helium reserves at a loss because politicians labeled it "party baloon reserve", and how long it takes to produce naturally and how hard it is to find, process and transport.
The US used to have a massive Strategic Helium Reserve [1]. Starting in the 1990s, Congress passed a law to sell down the reserve. This flooded the market with cheap Helium (yay, party balloons?) because the mandated pricing just didn't make any sense.
10-20 years ago there was a lot of talk about how this was foolish because it was depleting and squandering an unrenewable resource. But the thinking has shifted on that because it's an inevitable byproduct of natural gas production.
Now natural gas itself is limited but you can still get Helium from alpha decay of radioactive elements. Some elements are particularly strong alpha emitters (eg Polonium-210, Radium-223). They're basiclaly producing Helium constantly.
Helium is a known issue in various industries. The article notes (correctly) that MRI Helium use is decreasing because of the rise of so-called "Helium free" or "Helium light" MRI technology.
But there are short term supply issues. As noted, Qatar produces ~30% of the world's Helium currently. And that can (and has) been disrupted by recent events.
Lithography is a particularly important consumer of Helium for superconducting magnets. That demand is rising with probably no end in sight. Lithography itself is on the cutting edge of technology and engineering so seems harder to replace. I mean, EUV lithography is basically magic.
>The vast majority of MRI machines used today use superconducting magnets made from niobium-titanium (NbTi), which becomes superconducting at 9.2 degrees above absolute zero. This is well below the boiling point of any other coolant, making liquid helium the only practical option for cooling the magnets.
Well, this is part of it. The other issue is that the superconducting phase diagram has two limits: the transition temperature Tc and the upper critical magnetic field Hc. The magnetic field limit is generally highest at absolute zero and drops steeply with temperature. Even for the superconductors with Tc as high as 120 K the Hc at 20 K will be much less than the Hc at 4 K. So in order to make powerful superconducting magnets you need helium regardless of what superconductor you use, since nothing has broken this pattern.
The long tail economic ramifications that this disruption to the supply chain will have could be potentially decades, in ways that will most certainly be catastrophic, and what's concerning to me is how small of a percentage of the population (at least in the US) is grasping this.
Xenon is very rare too and currently without substitute for certain medical applications, but more interestingly it produces psychoactive effects that could shed light on stuff no other substance apparently can: https://pmc.ncbi.nlm.nih.gov/articles/PMC11203236/
The EUV lithography dependency is the one that worries me. MRI can reduce consumption 90%+ with zero-boiloff designs. Semiconductor fabs are moving in the opposite direction.. more helium per wafer as feature sizes shrink. That's not a recycling problem, it's a demand growth problem.
Waaay back in the early 1980s, I read an Asimov essay, “The Vanishing Element”, about the irreplaceable nature of helium and how badly humankind was wasting it. He pointed out that, once released, it just rises through the atmosphere and lost to space. I guess that chicken is coming home to roost.
Qatar produce(s/d) about a third of global helium. With the force majeure in place I won't be launching student HABs anytime soon. (Schools don't like hydrogen)
I did undergrad in Physics at the University of Florida. Some (many?) labs there did condensed matter experiments involving Helium 3. It's a million times more rare than normal helium. Nonrenewable, all that.
There was a dedicated system underground. Vacuum jacketed tubes taking waste helium from the labs to a reservoir across campus.
We need the price of helium to skyrocket otherwise it won't be valued at all. If another blimp or balloon is never produced again, I wouldn't blink an eye, it should be reserved for medical and scientific purposes since we can't manufacture it in large quantities.
My son's life was saved when he had a severe asthma attack and helium treatment helped him recover. The doctor told us about helium scarcity and how much she hated party balloons. ;p It certainly is a precious resource.
I recently began wondering if a planet's helium supply could be the 'great filter'. As in, if a civilization could stall out due to not having access to enough helium to product the technology to access off-world helium.
Helium is something that industry has become accustomed to wasting, flagrantly and dismissivly as a "byproduct", by industry that of course means the military and governments exercising there "discretion" in the service of money.
And it is the custom of bieng dissmissive that may (likely) be behind the many magnificent piles of rubble that litter the ancient world.
A short dip into how the soviets went about capturing certain other nobel gases is educational, when "hard" means something entirely else.
On June 27, 2024, the Biden Administration announced the final sale and transferring of the U.S. government’s remaining helium reserve to Messer LLC, a subsidiary of a German industrial gas business group with operations in China.
273 comments
I'm not a chemist but are there really no alternatives? Running fusion plants to make helium seems very unlikely to become cost effective, but it would be quite the sci-fi future if we filled party balloons by bombarding hydrogen with free protons.
I guess there aren't any easy molecules to break apart to get helium either since its a noble gas. No hydrolyses type solutions because there aren't any molecules that incorporate helium. I guess radioactive decay, but even that is ultimately limited over long enough timescales.
> There are NO alternatives.
We use a lot in our MR scanners.
The tech is changing and magnets are using far far less.
Super-conduction at higher temperatures has made progress too.
So while you are right that nothing else stays liquid at those temps, we won’t be needing nearly as much helium in radiology in the next few years.
The new generation use something like 700ml of helium, where the standard was hundreds of litres. https://magneticsmag.com/siemens-healthineers-gets-fda-clear...
> So while you are right that nothing else stays liquid at those temps, we won’t be needing nearly as much helium in radiology in the next few years.
How many loans for MRI machines that require helium haven't been paid back yet?
They use a lot when installed, but rarely need top-ups.
They are shipped full of helium and chilled, but aren’t ramped up (so aren’t superconducting magnets until after commissioning).
All these "we're going to run out" stories pretend that engineering cannot adapt to changing cost structures, which is just total nonsense.
Sure, there is nothing that can be directly substituted for how we use Helium today, but clearly we're using Helium inefficiently today and the answer is that once markets force us to change, we will find more efficient ways.
> It becomes a larger problem as the world moves away from fossil fuels like natural gas.
I actually remember a similar problem from some compound that was mainly formed as a byproduct of some old Canadian nuclear reactor design. As the tech gets phased out, the material is no longer available in significant quantities, with consequences for a projects that need it (like Iter).
Some things can be cheap if they are produced as a byproduct, but very expensive if they have to be obtained directly.
> it would be quite the sci-fi future if we filled party balloons by bombarding hydrogen
How dangerous are party balloons filled with hydrogen? Not a whole balloon arch obviously.
One of the larger episodes was in 2012 in Armenia, where thousands of balloons exploded during a meeting, injuring 154 people, of which 4 seriously (the video is of poor quality): https://www.youtube.com/watch?v=jWEm2sS7Dw8
A smaller, more recent episode in India: https://www.youtube.com/watch?v=FH5JwHeKnZo
That's because the starting density of the hydrogen air mixes at near atmospheric pressure (such as in a balloon) is pretty low. Also, the balloon does not significantly contain the explosion, which reduces the danger a lot. I would not want to do it in a glass container.
Things can always go wrong. We probably shouldn't strive for 100% safety because they we'd spend our lives in a padded cell. But we also shouldn't assume things are safe because they're common or routine.
https://en.wikipedia.org/wiki/Triple-alpha_process
I would.
How does that bang compare to the bang from an equally-inflated balloon full of ordinary air?
ETA: I may be misremembering, the more I think about it, the more I recall that we did not use air, we did use pure oxygen. Not like it was hard to get (and we had lots more interesting stuff than that in the lab, this was the 80s...). But the outcome I do remember. The entire point of the experiment was to examine the difference between the individual pure elements and the mix. We expected the pure hydrogen to be far more interesting than it turned out.
https://www.youtube.com/watch?v=Rwbyl7ywfhk&list=PLLnAFJxOjz...
Hydrogen mixed with air or with oxygen produces an ear piercing supersonic detonation, exceedingly loud and unpleasant. Not recommended for demonstrations.
The instructors would bring out a helium balloon and a candle on a meter stick. The balloon goes pop, huzzah.
Then the twist. "Hey, wanna do it again?" All the kids would be like "meh, I guess?" They would then bring out a balloon full of hydrogen (maybe some oxygen too?). It would look identical to the first one, floating there tethered to the lab bench.
When the candle hit the second one, it made a white flash and a really sharp BANG. It was an order of magnitude louder, and you could hear the transient bouncing off the walls and echoing in the halls. It made an impression.
* https://www.youtube.com/watch?v=bjc6MgUY0BE
* https://podcasts.apple.com/us/podcast/now-theres-a-helium-sh...
* https://omny.fm/shows/odd-lots/now-theres-a-helium-shortage-...
When you hear about alpha decay of radioactive materials, that is the matter spitting off a highly ionized helium nucleus, freshly birthed into this world. That He nucleus rapidly steals electrons from matter, which is how it can be dangerous to human cells if ingested.
All of that helium underground is the result of alpha decay, and a single uranium-238 element will birth 8 helium atoms as it transitions through a series of metals and one gas (radon), then finally finding stability as Pb206. U235 will birth 7, becoming Pb207.
Anyways, found that fascinating. It's just happenstance that helium often gets blocked exiting the crust by the same sort of structures that block natural gas from escaping, and they are an odd-couple sharing little in common.
One other fun fact -- radon only has a half life of 3.8 days. Uranium becomes thorium becomes radium, then radon where it has an average 3.8 days to seep out of the Earth and into our basements, where it then becomes radioactive metals that attach to dust, get breathed in (or eaten) and present dangers. In the scale of things, crazy. Chemistry is fascinating.
https://indepthmag.com/hydrogen-dreamin/
https://m.youtube.com/watch?v=bjc6MgUY0BE
10-20 years ago there was a lot of talk about how this was foolish because it was depleting and squandering an unrenewable resource. But the thinking has shifted on that because it's an inevitable byproduct of natural gas production.
Now natural gas itself is limited but you can still get Helium from alpha decay of radioactive elements. Some elements are particularly strong alpha emitters (eg Polonium-210, Radium-223). They're basiclaly producing Helium constantly.
Helium is a known issue in various industries. The article notes (correctly) that MRI Helium use is decreasing because of the rise of so-called "Helium free" or "Helium light" MRI technology.
But there are short term supply issues. As noted, Qatar produces ~30% of the world's Helium currently. And that can (and has) been disrupted by recent events.
Lithography is a particularly important consumer of Helium for superconducting magnets. That demand is rising with probably no end in sight. Lithography itself is on the cutting edge of technology and engineering so seems harder to replace. I mean, EUV lithography is basically magic.
[1]: https://en.wikipedia.org/wiki/National_Helium_Reserve
>The vast majority of MRI machines used today use superconducting magnets made from niobium-titanium (NbTi), which becomes superconducting at 9.2 degrees above absolute zero. This is well below the boiling point of any other coolant, making liquid helium the only practical option for cooling the magnets.
Well, this is part of it. The other issue is that the superconducting phase diagram has two limits: the transition temperature Tc and the upper critical magnetic field Hc. The magnetic field limit is generally highest at absolute zero and drops steeply with temperature. Even for the superconductors with Tc as high as 120 K the Hc at 20 K will be much less than the Hc at 4 K. So in order to make powerful superconducting magnets you need helium regardless of what superconductor you use, since nothing has broken this pattern.
There was a dedicated system underground. Vacuum jacketed tubes taking waste helium from the labs to a reservoir across campus.
Helium is rare, helium 3 is precious.
But for some reason for Americans peace is never the preferred option.